96302-75-9Relevant academic research and scientific papers
Diastereoselective Epoxidation of Allylic Phosphine Oxides
Clayden, Jonathan,Collington, Eric W.,Egert, Ernst,McElroy, Andrew B.,Warren, Stuart
, p. 2801 - 2810 (2007/10/02)
Allylic phosphine oxides are epoxidised anti selectively by m-CPBA, but this selectivity can be reversed if the allylic phosphine oxide is also an allylic alcohol.
TRANSPOSITION OF ALLYLIC ALCOHOLS CONTROLLED BY THE Ph2PO GROUP: REAGENTS FOR α-HYDROXY-DIENE SYNTHESIS BY THE HORNER-WITTIG REACTION
Brown, Paul S.,McElroy, Andrew B.,Warren Stuart
, p. 249 - 252 (2007/10/02)
4-Hydroxy-2-alkenyldiphenylphosphine oxides, prepared by a phosphorus-controlled allylic rearrangement, give dianions and hence α-hydroxydienes (substitued penta-2,4-dienols) by the Horner-Wittig reaction.
