96303-87-6Relevant academic research and scientific papers
Application in asymmetric Morita-Baylis-Hillman reactions
McIteka, Lulama P.,Lobb, Kevin A.,Kaye, Perry T.
, p. 151 - 163 (2016/10/22)
N-Substituted 2-exo-hydroxybornyl-10-sulfonamides, prepared as potential chiral auxiliaries for use in asymmetric Morita-Baylis-Hillman (MBH) reactions, have been treated with acryloyl chloride to afford the corresponding 2-exo-Acrylate esters as MBH subs
ASYMMETRIC DIELS-ALDER REACTIONS: FACILE PREPARATION AND STRUCTURE OF SULFONAMIDO-ISOBORNYL ACRYLATES
Oppolzer, Wolfgang,Chapuis, Christian,Bernardinelli, Gerald
, p. 5885 - 5888 (2007/10/02)
The crystalline chiral auxiliaries 2, 3 and 4 were prepared from champhor-10-sulfonyl chlorides in 2 steps.Their readily accessible acrylates underwent efficient asymmetric Diels-Alder additions to cyclopentadiene, the topicity of wich agrees with X-ray evidence.
