96322-38-2Relevant academic research and scientific papers
Iridium(I) complexes containing bidentate pyrazolylgallate ligands. X-ray crystal structures of Ir(COD), 2, and 2
Nussbaum, Sophia,Rettig, Steven J.,Storr, Alan,Trotter, James
, p. 692 - 702 (2007/10/02)
The synthesis and characterization of a number of Ir(I) complexes incorporating bidentate, chelating, pyrazolylgallate ligands are described.Non-rigidity for some of the complexes in solution has been demonstrated by variable temperature 1H nmr studies.Crystal structures of three complexes, Ir(COD), 2, and 2 are reported and confirm the expected boat conformations for the six-membered M-(N-N)2-Ir rings (where M = Ir or Ga) in the compounds.One of the complexes studied has exhibited measurable activity as a catalyst in the hydrogenation reaction of cyclohexene.
