96335-77-2Relevant articles and documents
Photolysis of alkylhalodiazirines: Two pathways for vinyl halide formation
La Villa, Joseph A.,Goodman, Joshua L.
, p. 5109 - 5112 (2007/10/02)
Photoacoustic calorimetry and product studios on the photochemical decomposition of methylhalodiazirines indicate two pathways for the formation of vinyl halides: 1) a [1,2] intramolecular hydrogen shift of the initially formed methylhalocarbene, 2) an excited state pathway which circumvents the ground state carbene. Results suggest that carbene/olefin or carbene/alcohol complexes are not involved in vinyl halide formation.