96335-95-4

Upstream product

• 7205-94-9 chloromethyl phenyl sulfoxide 
• 107-08-4 1-iodo-propane 

Downstream Products

• 146232-37-3 4-Benzenesulfinyl-4-chloro-1-phenyl-heptan-3-ol 
• 90919-67-8 1-Chlor-1-phenylmercapto-but-1-en 
• 114501-42-7 2-Benzenesulfinyl-2-propyl-1-oxa-spiro[2.5]octane 
• 129801-05-4 2-Benzenesulfinyl-2-propyl-1-oxa-spiro[2.6]nonane 
• 134670-85-2 2-Benzenesulfinyl-6-tert-butyl-2-propyl-1-oxa-spiro[2.5]octane 
• 122128-96-5 (1R*,2R*)-1-chloro-2-hydroxy-1-propylundecyl phenyl sulfoxide 
• 122128-95-4 (R*)-1-chloro-1-<(R*)-1-hydroxybenzyl>butyl phenyl sulfoxide 
• 122128-98-7 4-chloro-4-phenylsulfinyltetradecan-5-one 
• 122129-00-4 (2R,3R)-2-Benzenesulfinyl-3-nonyl-2-propyl-oxirane 
• 122128-97-6 2-chloro-1-phenyl-2-phenylsulfinylpentan-1-one 
• 122128-99-8 (2R,3R)-2-Benzenesulfinyl-3-phenyl-2-propyl-oxirane 
• 144882-79-1 4-chloro-1-phenyl-4-(phenylsulfinyl)-3-heptanone 
• 144882-94-0 (E)-4-chloro-1-phenyl-4-(phenylsulfinyl)-1-hepten-3-one 
• 122128-95-4 (R*)-1-chloro-1-<(S*)-1-hydroxybenzyl>butyl phenyl sulfoxide 

Relevant academic research and scientific papers

A Straightforward Homologation of Carbon Dioxide with Magnesium Carbenoids en Route to α-Halocarboxylic Acids

The homologation of carbon dioxide with stable, (enantiopure) magnesium carbenoids constitutes a valuable method for preparing α-halo acid derivatives. The tactic features a high level of chemocontrol, thus enabling the synthesis of variously functionalized analogues. The flexibility to generate magnesium carbenoids through sulfoxide-, halogen- or proton- Mg exchange accounts for the wide scope of the reaction. (Figure presented.).