96390-94-2Relevant academic research and scientific papers
Dinuclear p-Cymeneosmium Hydride Complexes; the Measurement of (187)Os Chemical Shifts using (1)H- Two-dimensional N.M.R. Spectroscopy
Cabeza, Javier A.,Mann, Brian E.,Brevard, Christian,Maitlis, Peter M.
, p. 65 - 67 (1985)
The reaction of (pc = η6-p-cymene, 4-isopropyltoluene) with propan-2-ol gives , but only in the presence of a salt (KPF6); J((187)Os-H) between 60.8 and 83.3 Hz have been measured for this complex and for (1+) (X=Y=H; X=H, Y=OAc; and X=OAc, Y=Cl) with the (187)Os chemical shift of , > at δ -2526 p.p.m. (referenced to OsO4), as measured by (1)H- two-dimensional n.m.r. spectroscopy, confirming the structures.
Mononuclear η6-p-Cymeneosmium(II) Complexes and their Reactions with Al2Me6 and other Methylating Reagents
Cabeza, Javier A.,Maitlis, Peter M.
, p. 573 - 578 (2007/10/02)
An improved-yield synthesis of the η-p-cymeneosmium(II) chloride complex (1) has allowed the development of the chemistry of the mononuclear complexes, (2) .Thes
