96393-05-4

Upstream product

• 107-20-0 2-chloroethanal 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 105660-54-6 (R)-N-(1-phenylethyl)ammonium (R)-N-(1-phenylethyl)dithiocarbamate 

Relevant academic research and scientific papers

The near infra red (NIR) chiroptical properties of nickel dithiolene complexes

Enantiomerically pure dianionic, monoanionic and neutral dithiolene complexes formulated as [Ni((R,R)-CHMePh-thiazdt)2]-2,-1,0 and [Ni((S,S)-CHMePh-thiazdt)2]-2,-1,0 (CHMePh-thiazdt: N-(1-phenylethyl)-1,3-thiazoline-2-thione-4,5-dithiolate) have been synthesized from the enantiopure N-(1-phenylethyl)-1,3-thiazoline-2-thione precursors. The electrochemical and spectro-electrochemical investigations carried out on these complexes show that the CHMePh-thiazdt ligands act as electron rich ligands and that the complexes are strong near infrared (NIR) absorbers in the range of 800-1100 nm for the neutral species and 1050-1500 nm for the reduced radical anion species. Circular dichroism (CD) thin layer spectro-electrochemical experiments carried out on the neutral (R,R) enantiomer, [Ni((R,R)-CHMePh-thiazdt)2], revealed a redox switching of CD-active bands, not only in the UV-vis but also in the NIR region.

Conformational Analysis of N-(1-Phenylethyl)-Δ4-thiazoline-2-thiones and Analogues. A 1H NMR, Circular Dichroism, X-ray Crystallographic, and Molecular Mechanics Study

The conformations of eleven N-(1-phenylethyl)thiazoline-2-thiones and three N-(1,2,3,4-tetrahydro-1-naphthyl) analogues with a variety of substituents in positions 4 and 5 have been studied by temperature-dependent 1H NMR and CD spectra, by empirical forc