96410-90-1

Upstream product

• 3141-05-7 1,2,3,4-tetraphenylfulvene 

Downstream Products

• 96410-94-5 tricarbonyl[1,2,3,4-tetraphenyl-5-[(trimethylphosphonio)methyl]cyclopentadienyl]molybdate 
• 96410-98-9 tricarbonyl[1,2,3,4,-tetraphenyl-5-[2-(triphenylphosphonio)ethyl]cyclopentadienyl]molybdate 
• 96410-96-7 tricarbonyl[1-[(dimethylphenylphosphonio)methyl]-2,3,4,5-tetraphenylcyclopentadienyl]molybdate 
• 96410-95-6 tricarbonyl[1,2,3,4-tetraphenyl-5-[(tributylphosphonio)methyl]cyclopentadienyl]molybdate 

Relevant academic research and scientific papers

Transition Metal Fulvene Complexes, XXIII. Tricarbonyl Fulvene and Tricarbonyl Cyclopentadienyl Complexes of Molybdenum and Tungsten

In contrast to the reaction of fulvenes with (CH3CN)3Cr(CO)3, which leads to pure (fulvene)Cr(CO)3 complexes, the reaction of L3M(CO)3 with fulvenes gives a mixture of (fulvene)M(CO)3 (2) and substituted dimeric (cyclopentadienyl)2M2(CO)6 complexes (3) difficult to separate.The structure of bis(η5-benzhydrylcyclopentadienyl)-hexacarbonyldimolybdenum (3a) has been determined by X-ray diffraction.The (fulvene)Mo(CO)3 complex 4 reacts with tertiary phosphanes and methylenetriphenylphosphorane to give the zwitterionic addition products 5 and 6.