96481-90-2Relevant academic research and scientific papers
Oxidation of diols by cetyltrimethylammonium dichromate
Patel, Sabita,Sung, Dae Dong,Mishra
experimental part, p. 1218 - 1221 (2009/03/11)
The oxidation kinetics of some diols have been investigated using cetyltrimethylammonium dichromate as the oxidant in dichloromethane in the presence of acetic acid and a cationic surfactant. A tentative mechanism has been proposed on the basis of (i) observed rate constant dependencies on the reactants, (ii) high negative entropy change and (iii) the kobs dependencies on surfactant concentration.
