96482-07-4Relevant academic research and scientific papers
Stereocontrolled Synthesis of Tetrahydrofurans and Tetrahydropyrans Using Thallium(III)-Induced Cyclizations
Michael, Joseph P.,Ting, Pauline C.,Bartlett, Paul A.
, p. 2416 - 2423 (2007/10/02)
Various substituted 4-alkenols undergo electrophilic cyclization with thallium(III) salts in a regio- and stereoselective manner. The organothallium intermediate is not isolated but undergoes dethallation with concomitant 1,2-oxygen migration, leading to
