96488-04-9Relevant academic research and scientific papers
ASYMMETRIC WITTIG SIGMATROPIC REARRANGEMENT INVOLVING A CHIRAL AZAENOLATE AS THE MIGRATING TERMINUS. A SIMPLE SYNTHESIS OF (+)-VERRUCARINOLACTONE
Mikami, Koichi,Fujimoto, Katsuhiko,Kasuga, Takashi,Nakai, Takeshi
, p. 6011 - 6014 (2007/10/02)
The diastereo- and/or enantioselection are described in the title rearrangement of the chiral 2-(2-alkenyloxy)methyl 2-oxazolines which eventually provides optically active α-hydroxy γ,δ-unsaturated esters and (+)-verrucarinolactone.
