96530-15-3

Upstream product

• 67957-90-8 1-(phenylthio)-2-methylcyclopentene 
• 136339-09-8 (6-Iodo-hexa-1,2-diene-3-sulfinyl)-benzene 
• 765-69-5 2-Methylcyclopentane-1,3-dione 
• 56671-87-5 3-Bromo-2-methylcyclopent-2-en-1-one 
• 82909-44-2 2-methyl-3-phenylsulfanyl-cyclopent-2-enone 
• 931-59-9 benzenesulfenyl chloride 
• 136339-36-1 (6-Chloro-hexa-1,2-diene-3-sulfinyl)-benzene 
• 1002-37-5 6-chloro-2-hexyn-1-ol 
• 96530-16-4 2-methyl-3-phenylthio-2-cyclopentenol 

Relevant academic research and scientific papers

Radical cyclizations of functionalized allenes

Substitution of P(O)Ph2, SOPh, and SO2Ph on an allene facilitates intramolecular radical addition to the central allene carbon to provide good yields of five-, six-, and seven-membered carbocycles.

Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α,β-unsaturated Cyclic Ketones

5,5,Dimethyl-3-phenoxy-2-cyclohexenone (Ib) was reduced with lithium aluminum hydride (LAH) to give the 1,2-addition product (IIIa). 2-Methyl-3-phenoxy-2-cyclopentetnone (IIa) gave a mixture of the allyl alcohol (IVa) and 1,2-addition product (IVb).On the