96530-38-0Relevant academic research and scientific papers
Unsaturated Carbohydrates. Part 27. Synthesis of (-)-exo-Brevicomin from a Nona-3,8-dienulose Derivative
Ferrier, Robert J.,Schmidt, Peter,Tyler, Peter C.
, p. 301 - 304 (2007/10/02)
The (-)-enantiomer (11) of the insect pheromone (+)-exo-brevicomin has been synthesized directly by hydrogenation-hydrogenolysis of the L-lyxo-nona-3,8-dienulose derivative (10).Epoxide ring opening of the methyl 3,4-anhydro-D-galactopyranoside (6), which
The formation of branched-chain deoxypentofuranosides by ring contraction in the reductive desulfonyloxylation of hexopyranoside p-toluenesulfonates
Baer, Hans H.,Astles, David J.,Chin, Ho-chi,Siemsen, Lisa
, p. 432 - 439 (2007/10/02)
Several methyl 6-deoxy-, 6-deoxy-6-halo-, and 6-O-p-tolylsulfonylhexopyranoside 2- and 4-p-toluenesulfonates reacted readily with lithium triethylborohydride in boiling tetrahydrofuran under reductive desulfonyloxylation at C-2 and C-4, respectively, and
