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The complex chemical compound [Rh2(Cl)(CO)2(C3HN2(CH2P(C6H5)2)2)] is a rhodium-based organometallic complex. It consists of two rhodium atoms, each coordinated with a chloride ion, two carbon monoxide molecules, and two bidentate ligands. These bidentate ligands are composed of a pyridine ring (C3HN2), a methylene group (CH2), and two diphenylphosphine groups (P(C6H5)2). The structure of [Rh2(Cl)(CO)2(C3HN2(CH2P(C6H5)2)2)] is characterized by its chelating nature, where the bidentate ligands bind to the rhodium atoms through two separate donor atoms, enhancing the stability of the complex. This type of compound is often studied for its potential applications in homogeneous catalysis and as a model for understanding the behavior of transition metal complexes in various chemical reactions.

96532-16-0

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96532-16-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 96532-16-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,5,3 and 2 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 96532-16:
(7*9)+(6*6)+(5*5)+(4*3)+(3*2)+(2*1)+(1*6)=150
150 % 10 = 0
So 96532-16-0 is a valid CAS Registry Number.

96532-16-0Relevant academic research and scientific papers

Bimetallic reactivity. Synthesis of bimetallic complexes containing a bis(phosphino)pyrazole ligand

Schenck, Terry G.,Downes,Milne,Mackenzie, Peter B.,Boucher, Heather,Whelan, John,Bosnich

, p. 2334 - 2337 (2008/10/08)

The ligand PNNHP has been prepared. It is a planar quadridentate ligand consisting of a central pyrazole unit with symmetrically disposed methylenediphenylphosphine arms, and its geometry provides for two metals to reside within cooperative distance but does not allow for metal-metal bond formation. Two types of planar bimetallic complexes have been isolated and characterized: those with anionic bridging groups (X) of the composition [M2(PNNP)(X)L2] (M = Pd(II), X = Cl, L = Cl; M = Rh(I), X = Cl and PPh2, L = CO; M = Ir(I), X = PPh2, L = CO) and those without bridging atoms of the composition [M2(PNNP)L4]+ (M = Pd(II), 2L = π-allyl; M = Rh(I) and Ir(I), 2L = diene and L = CO) have been identified.

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