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The chemical compound in question is a rhodium-based complex, specifically a cationic rhodium(I) complex with the formula [Rh2(C7H8)2(C3HN2(CH2P(C6H5)2)2)]+, which is paired with a tetrafluoroborate anion, BF4-, to form the neutral salt [Rh2(C7H8)2(C3HN2(CH2P(C6H5)2)2)]BF4. The complex consists of two rhodium atoms, each coordinated to two cycloheptatrienyl (C7H8) ligands and two bidentate diphosphine ligands, which are derived from 2-(diphenylphosphino)ethyl-1,3-diaminopropane (C3HN2(CH2P(C6H5)2)2). The overall structure is a rhodium dimer bridged by these ligands, with the tetrafluoroborate counterion balancing the charge of the cationic complex. This type of complex is often used in homogeneous catalysis due to the unique electronic and steric properties conferred by the rhodium center and the surrounding ligands.

96532-18-2

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96532-18-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 96532-18-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,5,3 and 2 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 96532-18:
(7*9)+(6*6)+(5*5)+(4*3)+(3*2)+(2*1)+(1*8)=152
152 % 10 = 2
So 96532-18-2 is a valid CAS Registry Number.

96532-18-2Relevant academic research and scientific papers

Bimetallic reactivity. Synthesis of bimetallic complexes containing a bis(phosphino)pyrazole ligand

Schenck, Terry G.,Downes,Milne,Mackenzie, Peter B.,Boucher, Heather,Whelan, John,Bosnich

, p. 2334 - 2337 (2008/10/08)

The ligand PNNHP has been prepared. It is a planar quadridentate ligand consisting of a central pyrazole unit with symmetrically disposed methylenediphenylphosphine arms, and its geometry provides for two metals to reside within cooperative distance but does not allow for metal-metal bond formation. Two types of planar bimetallic complexes have been isolated and characterized: those with anionic bridging groups (X) of the composition [M2(PNNP)(X)L2] (M = Pd(II), X = Cl, L = Cl; M = Rh(I), X = Cl and PPh2, L = CO; M = Ir(I), X = PPh2, L = CO) and those without bridging atoms of the composition [M2(PNNP)L4]+ (M = Pd(II), 2L = π-allyl; M = Rh(I) and Ir(I), 2L = diene and L = CO) have been identified.

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