96532-22-8

Upstream product

• 96532-20-6 [Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*CH₃OH=[Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*CH₃OH 
• 65567-06-8 lithium diphenylphosphide 

Downstream Products

• 96532-30-8 [Ir₂(P(C₆H₅)2)(CO)2(CH₃)I(C₃HN₂(CH₂P(C₆H₅)2)2)] 
• 96532-31-9 2Ir⁽³⁺⁾*P(C₆H₅)2^(1-)*2CO*2CH₃^(1-)*2I^(1-)*C₃HN₂(CH₂P(C₆H₅)2)2^(1-)*C₄H₁₀O=C₄₅H₄₁I₂N₂O₂P₃Ir₂*C₄H₁₀O 

Relevant academic research and scientific papers

Bimetallic reactivity. Synthesis of bimetallic complexes containing a bis(phosphino)pyrazole ligand

The ligand PNNHP has been prepared. It is a planar quadridentate ligand consisting of a central pyrazole unit with symmetrically disposed methylenediphenylphosphine arms, and its geometry provides for two metals to reside within cooperative distance but does not allow for metal-metal bond formation. Two types of planar bimetallic complexes have been isolated and characterized: those with anionic bridging groups (X) of the composition [M2(PNNP)(X)L2] (M = Pd(II), X = Cl, L = Cl; M = Rh(I), X = Cl and PPh2, L = CO; M = Ir(I), X = PPh2, L = CO) and those without bridging atoms of the composition [M2(PNNP)L4]+ (M = Pd(II), 2L = π-allyl; M = Rh(I) and Ir(I), 2L = diene and L = CO) have been identified.