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The given chemical is a complex rhodium compound, denoted as [Rh2(P(C6H5)2)(CO)2(CH3CO)2(Cl)2(C3HN2(CH2P(C6H5)2)2)]*1.5CH2Cl2. [Rh2(P(C6H5)2)(CO)2(CH3CO)2(Cl)2(C3HN2(CH2P(C6H5)2)2)]*1.5CH2Cl2 consists of a rhodium core with two rhodium atoms, each coordinated to two triphenylphosphine (P(C6H5)2) ligands, two carbonyl (CO) ligands, two acetate (CH3CO) ligands, two chloride (Cl) ligands, and two 2,6-diacetylpyridine-bis(diphenylphosphine) (C3HN2(CH2P(C6H5)2)2) ligands. The entire complex is associated with 1.5 equivalents of dichloromethane (CH2Cl2) solvent molecules. This complex is likely to be used in homogeneous catalysis, given the presence of rhodium and phosphine ligands, which are common in such applications.

96532-27-3

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96532-27-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 96532-27-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,5,3 and 2 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 96532-27:
(7*9)+(6*6)+(5*5)+(4*3)+(3*2)+(2*2)+(1*7)=153
153 % 10 = 3
So 96532-27-3 is a valid CAS Registry Number.

96532-27-3Downstream Products

96532-27-3Relevant academic research and scientific papers

Bimetallic reaetivity. Oxidative-addition and reductive-elimination reactions of rhodium and iridium bimetallic complexes

Schenck, Terry G.,Milne,Sawyer,Bosnich

, p. 2338 - 2344 (2008/10/08)

Homobimetallic complexes of rhodium(I) and iridium(I) containing the binucleating ligand PNNP undergo oxidative-addition and reductive-elimination reactions with acetyl chloride and methyl iodide. Depending on the electron richness of the metals, a complete spectrum of possibilities is observed from reversible single oxidative addition on one of the metals to irreversible double oxidative addition on both metals. Oxidative addition to one metal leads to deactivation of the other metal despite the fact that no metal-metal bonds are formed. A crystal structure of a rhodium(I)-rhodium(III) complex [Rh2(μ-PPh2)(CO)2PNNP-(CH 3)I]·C4H10O has been determined and shows the two metals to be separated by 3.766 A?. Crystals are triclinic, space group P1, a = 12.211 (4) A?, b = 13.313 (7) A?, c = 15.616 (7) A?, a = 79.34 (5)°, α = 72.64 (3)°, γ = 84.37 (4)°, V = 2379 A?3, Dcalcd = 1.57 g cm-3 for Z = 2, and R = 0.0401 for 6739 observed (I > 3σ(I)) reflections. The bis(diene) species of rhodium and iridium are precursors for catalytic hydrogenation of alkenes and alkynes.

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