96548-50-4

Upstream product

• 96548-47-9 2,2'-dichloro-N,N':N,N'-bis(3-thiapentane-1,5-diyl)bis(acetamid) 
• 65113-45-3 1,7-diaza-4,10-dithiacyclododecane 
• 603-35-0 triphenylphosphine 
• 96548-48-0 4,10-bis(2-chloroethyl)-1,7-dithia-4,10-diazacyclododecane 
• 15475-27-1 potassium diphenylphosphine 

Relevant academic research and scientific papers

Ditopic Ligands. The Synthesis of a Series of Phosphine-Functionalised Macrocycles

The synthesis of a series of phosphine-functionalised macrocycles, 1-6, is described.The combination of N- and O-sites with P- and S-sites provides ligands which may bind transition or non-transition metal ions; as a consequence, they give access to dinuclear complexes containing both a Lewis acid and a redox metallic site.Compounds 1,2 and 6 are heterodinucleating ligands capable of binding two dissimilar metals in proximity.Macrocycles 3-5 are homotopic ligands which may form homodinuclear complexes of transition metals.

Heterotopic Ligands: Synthesis and Complexation Properties of Phosphine-functionalized Dipodal Macrocycles

The synthesis of a series of phosphine-functionalized dipodal macrocycles is described; prior co-ordination of a cation within the macrocyclic cavity regulates the ligand structure aiding formation of heterodinuclear complexes.