96549-22-3Relevant academic research and scientific papers
RING OPENING OF BENZOXAZOLES WITH ALLYLIC GRIGNARD REAGENTS: SYNTHESIS OF N-DIALLYLALKYL-o-AMINOPHENOLS.
Florio, Saverio,Epifani, Erbana,Ingrosso, Giovanni,Sgarra, Riccardo
, p. 5089 - 5096 (2007/10/02)
The title benzoxales 1a-d react cleanly with allylic Grignard reagents 2a-c undergoing ring opening to give good yields of N-diallyl-alkyl-o-aminophenols 3a-m.A plausible mechanism is discussed.
