96556-01-3Relevant academic research and scientific papers
Oligomerization of Vinyl Monomers. 17. Stereoselective Methylation of 1-Lithio-1,3-bis(phenylsulfinyl)butane. Kinetic vs. Thermodynamic Control in the Formation of Diastereomeric Ion Paors
Buese, Mark A.,Hogen-Esch, Thieo E.
, p. 4509 - 4513 (2007/10/02)
The addition of (R) or (R,S)-vinyl phenyl sulfoxide (3) to (R)- or (R,S)-1-lithio-(phenylsulfinyl)ethane (2) was carried out in THF at -78 deg C, and the adduct anion 4 was protonated or methylated to produce 1,3-bis(phenylsulfinyl)butane (6) or 2,4-bis(p
