96558-51-9

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 616-24-0 3-aminopentane 
• 29546-14-3 4-((1H-benzo[d][1,2,3]triazol-1-yl)methyl)-N,N-dimethylaniline 
• 156602-64-1 [4-(1-Benzotriazol-1-yl-1-ethyl-propyl)-phenyl]-dimethyl-amine 
• 925-90-6 ethylmagnesium bromide 
• 100-10-7 4-dimethylamino-benzaldehyde 

Relevant academic research and scientific papers

Benzotriazole-mediated synthesis of α-di- and α-trisubstituted ethers and sulfides

Ethylaryl- and diethylaryl(benzotriazol-1-yl)methanes, obtained by mono- or dialkylation of substituted (benzotriazol-1-ylmethyl)benzenes, react with sodium alkoxides, phenol and thiophenol to yield the corresponding α-di- and α-trisubstituted ethers and

Nucleophilic Displacement with Heterocycles as Leaving Groups. Part 16. Reactions of Secondary Alkyl Primary Amines with 5,6,8,9-Tetrahydro-7-phenyldibenzoxanthylium Trifluoromethanesulphonate to give Intermediates Solvolysing without Rearrangement

Representative secondary alkyl primary amines R1R2CHNH2 react with the title pyrylium cation in acetic acid, alcohols, phenols, and NN-dimethylaniline acting as nucleophilic solvents to give O- and C-(secondary alkyl) products.Absence of carbenium ion rearrangements is consistent with reaction via intimate ion-molecule pairs formed rapidly from the corresponding pyridinium cations.