96569-52-7Relevant academic research and scientific papers
Reaction of Trifluoromethyl Ketones. IV. Cyclization of the Ene Reaction Products of Trifluoromethyl Ketones: A Facile Synthesis of 2-(Trifluoromethyl)tetrahydrofuran
Nagai, Takabumi,Miki, Takuichi,Kumadaki, Itsumaro
, p. 3620 - 3627 (2007/10/02)
1-(Trifluoromethyl)homoallyl alcohols, which were obtained by the ene reaction of trifluoromethyl ketones with olefins, were cyclized to 2-(trifluoromethyl)tetrahydrofurans in the presence of p-toluenesulfonic acid, a typical Brensted acid.The ease of thi
Studies on Organic Fluorine Compounds. XLIII. The Ene Reaction on Hexafluoroacetone
Kobayashi, Yoshiro,Nagai, Takabumi,Kumadaki, Itsumaro
, p. 5031 - 5035 (2007/10/02)
The reaction of hexafluoroacetone with phenyl-substituted allyl compounds was found to give the ene products.Thus, allylbenzene gave 1,1,1-trifluoro-5-phenyl-2-(trifluoromethyl)pent-4-en-2-ol.Allyl phenyl ether and thioether gave the corresponding ene pro
