96575-62-1Relevant academic research and scientific papers
A new mild procedure for the direct coupling of 1-trimethylsilyl acetylenes with vinyl triflates or aryl iodide
Halbes, Ulla,Pale, Patrick
, p. 2039 - 2042 (2007/10/03)
1-Trimethylsilyl acetylenes can be directly coupled with vinyl triflates or aryl iodide in the presence of the appropriate amount of potassium carbonate and methanol and a catalytic amount of AgCl and Pd(PPh3)4. Functionalized enynes can thus be obtained in good to excellent yields without prior deprotection of the alkyne.
Palladium-Catalyzed Olefination of Vinyl Triflates
Scott, William J.,Pena, Michael R.,Swaerd, Katarina,Stoessel, Steven J.,Stille, J. K.
, p. 2302 - 2308 (2007/10/02)
The olefination of vinyl trifluoromethanesulfonates (triflates) takes place under mild reaction conditions in polar solvents to give high yields of conjugated dienes.The reaction of 4-tert-butylcyclohexenyl triflate with Michael acceptors in the presence
