96599-48-3Relevant academic research and scientific papers
Rate Enhancement in Ethanolic Aqueous Buffer. The Diels-Alder Reaction
Smith, Michael B.,Fay, Joseph N.,Son, Young Chan
, p. 2451 - 2454 (2007/10/02)
We have observed a 2.5 - 3-fold increase in the rate of Diels-Alder reactions when done in aqueous ethanol, where the aqueous solution was prepared with a pH 7 buffer.This is a simple, inexpensive and convenient method for modest acceleration of the Diels
5-ALKYLIDENE-HEXAHYDRO-1H-CYCLOPENTAPYRROL-1,3-DIONES BY NICKEL(0) OR PALLADIUM(0) CATALYZED CYCLOADDITION OF METHYLENECYCLOPROPANES WITH MALEIMIDES
Binger, Paul,Freund, Andreas,Wedemann, Petra
, p. 2887 - 2894 (2007/10/02)
Nickel(0) catalyzed cycloaddition of methylenecyclopropanes 1a-e with N-substituted maleimide 3b (R = CH3) and 3c (R = Ph) leads almost exclusively to the title compounds 6 and 7.The same reaction occurs in the presence of a palladium(0) catalyst wi
