96609-50-6

Basic information

• Product Name: 1,3,2,4-Diazadiboretidine, 1,3-bis(1,1-dimethylethyl)-2,4-diethyl-
• CAS NO: 96609-50-6
• Molecular Formula: C12H28B2N2
• Molecular Weight: 221.99
• Mol File: 96609-50-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,2,4-Diazadiboretidine, 1,3-bis(1,1-dimethylethyl)-2,4-diethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2,4-Diazadiboretidine, 1,3-bis(1,1-dimethylethyl)-2,4-diethyl-(96609-50-6)
• EPA Substance Registry System: 1,3,2,4-Diazadiboretidine, 1,3-bis(1,1-dimethylethyl)-2,4-diethyl-(96609-50-6)

Safety Data

• Hazardous Substances Data: 96609-50-6(Hazardous Substances Data)

Upstream product

• 1739-53-3 ethyl-dichloro-borane 

Downstream Products

• 110472-73-6 3,5-di-tert-butyl-2,4-diethyl-6-(diphenylmethylene)-1-oxa-3,5-diazonia-2,4-diborata-2,4-cyclohexadiene 
• 110486-05-0 1,3-di-tert-butyl-2,4-diethyl-4-(phenylethynyl)-1,3-diazonia-2,4-diborata-1,3-butadiene 
• 134152-50-4 2,4,6,8-tetraethyl-1,3,5,7-tetraphenyl-1,3,5,7,2,4,6,8-tetrazatetraborocane 
• 134152-43-5 1,3,5-tribenzyl-2,4,6-triethylborazine 

Relevant articles and documents

Contributions to the Chemistry of Boron, 167. Synthesis of Diazadiboretidines, Borazines, and Octahydrotetrazatetraborocines via Stannazane Cleavage Reactions

Diazadiboretidines 2 are obtained from the diazadistannetidine 1 or 2NC(CH3)3 by Sn-N cleavage with boron halides RBX2 (R = CH3, C2H5, CH(CH3)2, C6H5, Cl, X = Cl, Br).Borazines 15 are formed, however, by Sn-N cleavage of 2NC(CH3)3 (12) with RBX2 (except with (CH3)2HCBCl2) in a 1:1 ratio. (Stannylamino)boranes are NMR detectable intermediates. - The diazadiboretidines 2 2b - d (R = C2H5, CH(CH3)2, C6H5) do not dimerize in contrast to 2a (R = CH3).The equilibrium constant has been determined for the equilibrium 2a 6, the formation of the dimer obeying a second order rate law. 2 (2e) is metastable at -20 deg C.It forms 4 (8) irreversibly at 20 deg C. - 6 crystallizes in the monoclinic system, space group P21/c.The tubshaped molecule possesses alternating single and double BN bonds (BN: 1.516, 1.404 Angstroem).