96642-94-3

Upstream product

• 96642-93-2 Phenoxy-acetic acid (S)-1-((R)-3-hydroxy-1-methyl-propyl)-4-methyl-pent-3-enyl ester 
• 96642-87-4 3-[(R)-1-(1-Ethoxy-ethoxy)-ethyl]-6-methyl-2-trimethylsilanyl-hepta-1,5-dien-3-ol 
• 96642-92-1 Phenoxy-acetic acid (S)-4-methyl-1-((R)-1-methyl-allyl)-pent-3-enyl ester 
• 96642-89-6 Methanesulfonic acid (R)-2-hydroxy-1,5-dimethyl-2-(1-trimethylsilanyl-vinyl)-hex-4-enyl ester 
• 96642-93-2 Phenoxy-acetic acid (R)-1-((S)-3-hydroxy-1-methyl-propyl)-4-methyl-pent-3-enyl ester 
• 96642-87-4 3-[(S)-1-(1-Ethoxy-ethoxy)-ethyl]-6-methyl-2-trimethylsilanyl-hepta-1,5-dien-3-ol 
• 96642-92-1 Phenoxy-acetic acid (R)-4-methyl-1-((S)-1-methyl-allyl)-pent-3-enyl ester 
• 96642-89-6 Methanesulfonic acid (S)-2-hydroxy-1,5-dimethyl-2-(1-trimethylsilanyl-vinyl)-hex-4-enyl ester 
• 96642-88-5 (S)-6-Methyl-3-(1-trimethylsilanyl-vinyl)-hept-5-ene-2,3-diol 
• 96642-90-9 (R)-3,7-Dimethyl-2-trimethylsilanyl-octa-1,6-dien-4-one 
• 96642-91-0 (3R,4R)-3,7-Dimethyl-2-trimethylsilanyl-octa-1,6-dien-4-ol 
• 96687-84-2 (3S,4R)-3,7-Dimethyl-octa-1,6-dien-4-ol 
• 96642-88-5 (R)-6-Methyl-3-(1-trimethylsilanyl-vinyl)-hept-5-ene-2,3-diol 
• 96642-90-9 (S)-3,7-Dimethyl-2-trimethylsilanyl-octa-1,6-dien-4-one 

Relevant academic research and scientific papers

ENANTIO- AND DIASTEREO-CONTROLLED SYNTHESIS OF (+)- AND (-)-ELDANOLIDE BASED ON ASYMMETRIC PINACOL-TYPE REARRANGEMENT

Highly enentio- and diastereo-controlled synthesis of chiral pheromone, eldanolide, was accomplished in both enantiomeric forms, via organoaluminium-mediated asymmetric pinacol-type rearrangement followed by stereoselective reduction.