96695-31-7Relevant academic research and scientific papers
FUNCTIONALISATION OF UNACTIVATED METHYL GROUPS THROUGH CYCLOPALLADATION REACTIONS
Baldwin, Jack E.,Jones, Richard H.,Najera, Carmen,Yus, Miguel
, p. 699 - 712 (2007/10/02)
The transformation of the organopalladium compound (3) into the corresponding deuteriated, chlorinated, or oxidized derivatives (7), (8), or (9), (11), and (12) respectively, is described.The palladation of compound (9) takes place regioselectively leadin
Oxidation of Unactivated Methyl Groups via a Cyclopalladation Reaction
Baldwin, Jack E.,Najera, Carmen,Yus, Miguel
, p. 126 - 127 (2007/10/02)
The successive cyclopalladation-oxidation of E-pinacolone, E-2,2-dimethylcyclohexanone, 2,2,6,6-tetramethylcyclohexanone, and E-lupanone oxime led to the corresponding β-acetoxy derivatives; the second palladation in the case of the acetoxy compounds (2) and (8) takes place in one of the remaining methyl groups, being a regiospecific process, and in the case of the cyclic oximes the palladation occurs in the equatorial methyl group.
