96759-75-0

Upstream product

• 110366-53-5 Acetic acid (S)-2-methyl-3-((E)-3-p-tolylsulfanyl-allyl)-cyclopent-1-enyl ester 
• 1120-73-6 2-methyl-2-cyclopenten-1-one 
• 89708-79-2 (R)-(+)-allyl p-tolyl sulphoxide 
• 110416-47-2 <3(S),S(R)>-1-acetoxy-2-methyl-3-<(E)-3-(p-tolylsulfinyl)-2-propen-1-yl>-1-cyclopentene 

Downstream Products

• 111849-11-7 (3aR,6aS)-(3aα,6aα)-octahydro-6a-methyl-1-methylene-6-(p-tolylthio)pentalene 
• 111849-18-4 (3aR,6aS)-(3aα,6aα)-hexahydro-6a-methyl-6-(p-tolylthio)-1(2H)-pentalenone ethylene ketal 
• 59372-72-4 (+)-hirsutene 
• 111849-13-9 (3aR,6aS)-(3aα,6aα)-octahydro-6a-methyl-1-methylene-6-(p-tolylsulfinyl)pentalene 
• 111849-17-3 (3aR,6aS)-(3aα,6aα)-3,3a,4,5,6,6a-hexahydro-6a-methyl-6-methylene-1-(p-tolylsulfinyl)pentalene 
• 111849-15-1 (1R,3aR,6aS)-(3aα,6aα)-octahydro-1-bromo-6a-methyl-6-methylene-1-(p-tolylsulfinyl)pentalene 
• 111849-19-5 (3aR,6aS)-(3aα,6aα)-hexahydro-6a-methyl-6-(p-tolylsulfinyl)-1(2H)-pentalenone ethylene ketal 
• 111849-20-8 (3aS,6R,6aS)-(3aα,6aα)-2,3,3a,5,6,6a-hexahydro-6α-<2,2-dimethyl-3-(tosyloxy)propyl>-1,4-pentalenedione ethylene ketal 

Relevant academic research and scientific papers

Asymmetric Induction in the Addition Reactions of Chiral Sulfinylallyl Anions (Ambident Nucleophiles) with Enones (Ambident Electrophiles). Ring Closure of Enol Thioether Ketones

The regio- and stereochemical aspects of reactions of sulfinylallyl anions possessing chiral sulfur with various cyclic enones are reported.The 1,4-γ-adducts (Michael-type adducts) were obtained with excellent enantioselectivity in most cases (70-96percen