96845-71-5Relevant academic research and scientific papers
Preparation of 1-Aryl-2-siloxyalkynes from Silylated α-Diazo Carbonyl Compounds
Maas, Gerhard,Brueckmann, Ralf
, p. 2801 - 2802 (2007/10/02)
Silylated α-diazo carbonyl compounds R3SiC(N2)C(O)Ar, prepared from a monosubstituted α-diazo carbonyl compound with trialkylsilyl triflates, rearrange to 1-aryl-2-siloxyalkynes with loss of N2 at or above room temperature, this novel transformation is th
