96914-71-5

Basic information

• Product Name: [(1RS,3RS)-2,2,3-trimethylcyclopropyl]phenylmethanone
• Synonyms: [(1RS,3RS)-2,2,3-trimethylcyclopropyl]phenylmethanone
• CAS NO: 96914-71-5
• Molecular Weight: 188.269
• Mol File: 96914-71-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [(1RS,3RS)-2,2,3-trimethylcyclopropyl]phenylmethanone(CAS DataBase Reference)
• NIST Chemistry Reference: [(1RS,3RS)-2,2,3-trimethylcyclopropyl]phenylmethanone(96914-71-5)
• EPA Substance Registry System: [(1RS,3RS)-2,2,3-trimethylcyclopropyl]phenylmethanone(96914-71-5)

Safety Data

• Hazardous Substances Data: 96914-71-5(Hazardous Substances Data)

Upstream product

• 495-41-0 1-phenylbut-2-en-1-one 
• 1027607-76-6 triisopropyl sulfoxonium tetrafluoroborate 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 28273-55-4 potassium salt of 2-nitropropane 

Relevant articles and documents

An improved gem-dimethylcyclopropanation procedure using triisopropyl-sulfoxonium tetrafluoroborate

A new procedure for the cyclopropanation of α,β-unsaturated carbonyl compounds and related systems is described which employs triisopropylsulfoxonium tetrafluoroborate and sodium hydride in dimethylformamide. Using this reagent, a range of α,β-unsaturated ketones (and an ester and a vinyl nitro example) has been converted into the corresponding gem-dimethylcyclopropyl carbonyl compounds; in addition, a preliminary result is described in which an activated alcohol is converted directly into a gem-dimethylcyclopropyl ketone by a one-pot tandem oxidation-cyclopropanation sequence, albeit in low yield. Georg Thieme Verlag Stuttgart.

Nitro Compounds as Nucleophilic Alkylidene Transfer Reagents

Nitro compounds can be used as useful and general nucleophilic alkylidene transfer reagents for the preparation of various cyclopropanes.