96923-36-3Relevant academic research and scientific papers
ANCHIMERICALLY ASSISTED LEWIS ACID CLEAVAGE OF TETRAHYDROFURANS TO FURNISH 1,4-DIOLS
Harwood, Laurence M.,Jackson, Brian,Prout, Keith,Witt, Fiona J.
, p. 1885 - 1888 (2007/10/02)
Treatment of 3-aroyloxy- and 2-(aroyloxymethyl)tetrahydrofurans with TiCl4 results in cleavage of the heterocyclic ring with intervention by the appropriately situated ester group to form intermediates which, on work-up and hydrolysis, furnish 1,4-diols.
Synthese et hydrolyse d'orthoesters trioxa-2,7,8 bicyclo octanes et trioxa-2,8,9 bicyclo nonanes
Bouab, Otmane,Lamaty, Gerard,Moreau, Claude
, p. 816 - 822 (2007/10/02)
The rates of hydrolysis of 1-substituted 2,7,8-trioxabicyclo octanes and 2,8,9-trioxabicyclo nonanes (R = H, CH3, C6H5) have been determined at two temperatures in dioxan/water (60:40 by volume).These new results confirm the behaviour generally observed in the hydrolysis of orthoesters which have a favourable conformation to hydrolyze under stereoelectronic control.
