96930-22-2Relevant articles and documents
OPTICALLY ACTIVE α-ALKYLSUCCINATES FROM THE STEREOSELECTIVE ALKYLATION OF CHIRAL IMIDE ENOLATES.
Fadel, Antonine,Salauen, Jacques
, p. 6257 - 6260 (2007/10/02)
The chiral oxazolidinones 1 and 2 were alkylated by methyl bromoacetate, then subsequent removal of the chiral auxiliary provided readily with high stereoselectivity the α-alkylated succinates 7 and 8.Acyloin condensation and bromination gave the optically active α-t-butylcyclobutanedione 10.