97006-05-8

Upstream product

• 1217495-23-2 l-menthyl 2,5-dimethyl-2-phenyl-4-hexenoate 
• 1217494-71-7 l-menthyl 2-phenylpropanoate 
• 870-63-3 prenyl bromide 
• 34713-70-7 2-Phenylpropanal 
• 1015-18-5 rac-2,5-dimethyl-2-phenylhex-4-enal 

Downstream Products

• 1512853-94-9 rac-2,2,5-trimethyl-5-phenyltetrahydropyran 
• 51082-28-1 2-methyl-5-phenyl-2-hexene 
• 110458-30-5 2,5-Dimethyl-1,2-diphenyl-hex-4-en-1-one 

Relevant academic research and scientific papers

Diastereoselective synthesis of substituted hexahydrobenzo[de]isochromanes and evaluation of their antileishmanial activity

Hexahydrobenzo[de]isochromanes and hexahydropyrano[3,4,5-ij]isoquinolines can be efficiently synthesized via Friedel Crafts and oxa Pictet-Spengler reaction of acrylyl enol ethers mediated by triflic acid in good yields. The reaction is highly stereoselective. Two of the hexahydrobenzo[de]isochromanes are found to have moderate antileishmanial activity.

Sila-rhubafuran and derivatives: Synthesis and olfactory characterization of novel silicon-containing odorants

Sila-rhubafuran (1b), a silicon analogue of the grapefruit odorant rhubafuran (1a), was synthesized and isolated as a 1:1 mixture of two racemic diastereomers. In addition, the structurally related racemic C/Si pairs 2a/2b and 3a/3b were prepared. To get