97023-51-3

Basic information

• Product Name: (E)-1-acetoxyl-2-ethyl-3-phenyl-1-propene
• CAS NO: 97023-51-3
• Molecular Weight: 204.269
• Mol File: 97023-51-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-acetoxyl-2-ethyl-3-phenyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-acetoxyl-2-ethyl-3-phenyl-1-propene(97023-51-3)
• EPA Substance Registry System: (E)-1-acetoxyl-2-ethyl-3-phenyl-1-propene(97023-51-3)

Safety Data

• Hazardous Substances Data: 97023-51-3(Hazardous Substances Data)

Upstream product

• 104623-10-1 2-diacetoxymethyl-but-1-ene 
• 71-43-2 benzene 
• 10147-11-2 propargyl benzene 
• 925-90-6 ethylmagnesium bromide 
• 108-24-7 acetic anhydride 

Relevant articles and documents

Tandem carbocupration/oxygenation of terminal alkynes

(Chemical Equation Presented) A direct and general synthesis of α-branched aldehydes and their enol derivatives is described. Carbocupration of terminal alkynes and subsequent oxygenation with lithium tert-butyl peroxide generates a metallo-enolate. Trapping with various electrophiles provides α-branched aldehydes or stereo-defined trisubstituted enol esters or silyl ethers. The tandem carbocupration/ oxygenation tolerates alkyl and silyl ethers, esters, and tertiary amines. The reaction is effective with organocopper complexes derived from primary, secondary, and tertiary Grignard reagents and from n-butyllithium.