97049-72-4Relevant academic research and scientific papers
Iron-catalyzed selective oxidative arylation of phenols and biphenols
Vershinin, Vlada,Dyadyuk, Alina,Pappo, Doron
, p. 3660 - 3668 (2017)
The single-step synthesis of protected fucols and unnatural polyaryls by biomimetic oxidative cross-coupling between phenolic components and 1,3,5-trimethoxybenzene catalyzed by FeCl3 in fluorinated solvents is reported. The regioselectivity (o
Brown algal polyphenols: synthesis of "fucophlorethol A" octamethyl ether (2,2'4,6,6'-pentamethoxy-4'-(2,4,6-trimethoxyphenoxy)biphenyl)
Ragan, Mark A.
, p. 291 - 293 (2007/10/02)
Vanadium tetrachloride-catalyzed dimerization of 3,5-dimethoxyphenol yields the key intermediate 2,2',6,6'-tetramethoxy-4,4'-dihydroxybiphenyl, from which the octamethyl ether of the brown algal metabolite "fucophlorethol A" (2,2',4,6,6'-pentamethoxy-4'-(2,4,6-trimethoxyphenoxy)biphenyl,6) is synthesized by Ullmamm condensation and Hakomori methylation.
