97073-14-8Relevant articles and documents
The Rabe amination after a century: Direct addition of N-heterocycles to carbonyl compounds
Scarpino Schietroma, Daniele M.,Monaco, Mattia R.,Bucalossi, Valerio,Walter, Philipp E.,Gentili, Patrizia,Bella, Marco
supporting information; experimental part, p. 4692 - 4695 (2012/08/08)
A catalytic version of the Rabe electrophilic amination is presented. This kind of reaction was originally employed in 1918 in a key step for the conversion of quinotoxine to quinine. Ketones and α-substituted aldehydes give the corresponding α-aminated carbonyl compounds in moderate yield. α,α-Unsubstituted aldehydes give rise to amino ketones via a novel rearrangement.
Studies on the Oxidation of Enamines with Molecular Oxygen 2. Oxidation of 1-Amino But-1-enes
Blau, Karla,Kapst, Ulrike,Voerckel, V.
, p. 671 - 676 (2007/10/02)
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