97128-04-6

Basic information

• Product Name: bis(2,6-dimethylphenylisocyanide)(phthalocyaninato)iron(II)
• CAS NO: 97128-04-6
• Molecular Weight: 830.734
• Mol File: 97128-04-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(2,6-dimethylphenylisocyanide)(phthalocyaninato)iron(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2,6-dimethylphenylisocyanide)(phthalocyaninato)iron(II)(97128-04-6)
• EPA Substance Registry System: bis(2,6-dimethylphenylisocyanide)(phthalocyaninato)iron(II)(97128-04-6)

Safety Data

• Hazardous Substances Data: 97128-04-6(Hazardous Substances Data)

Upstream product

• 132-16-1 (phthalocyaninato)iron(II) 
• 119072-54-7 2,6-dimethylphenyl isonitrile 

Relevant articles and documents

(Phthalocyaninato)iron(II)- and -ruthenium(II) Compounds with Isocyanides as Axial Ligands

(Phthalocyaninato)iron(II) and -ruthenium(II) (PcM, M = Fe, Ru) react with aliphatic and aromatic monodentate isocyanides RNC (R = t-Bu, c-HX, Bzl, Ph, Me2ph) with formation of the corresponding bisaxial substituted (phthalocyaninato)metal(II) compounds PcM(RNC)2 (M = Fe, Ru) 1-5.The structures of these soluble compounds were determined by 1H and 13C NMR spectroscopy.The influence of the central metal atom M and of the organic group on the ?-donor-?-acceptor properties of the metal-ligand bonds is investigated by IR spectroscopy.UV/VIS spectroscopy , TG/DTG/DTA measurements and FD mass spectroscopy additionally demonstrate the large differences when changing iron against ruthenium in 1-5.The thermal and mass spectroscopic differences point to the existence of pentacoordinated PcRu(II) compounds.