97169-48-7Relevant academic research and scientific papers
Stereoselective synthesis of several azido/amino- and diazido/diamino-myo-inositols and their phosphates from p-benzoquinone
Podeschwa, Michael A.L.,Plettenburg, Oliver,Altenbach, Hans-Josef
, p. 1919 - 1929 (2007/10/03)
A practical route is described for the preparation of azido-myo-inositols, amino-myo-inositols and azido-conduritol B derivatives. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol B derivative. Selective introduction of nitrogen-containing functional groups in four of the six possible positions in the cyclitol moiety is followed by further functionalization to yield the target compounds.
Cyclitol Reactions, XII. - Enantioselective Synthesis of the Central Pseudodisaccharide Unit of α-Glycosidase Inhibitors of the Oligostatine Type
Paulsen, Hans,Roeben, Wolfgang
, p. 974 - 994 (2007/10/02)
A pseudodisaccharide unit of the α-glycosidase inhibitors of the oligostatine type has been synthesized.At first a synthesis of the enantiomeric pure derivative of the branched amino inositol 26 has been developed.A linkage of 26 with the reactive epoxide
