97183-33-0Relevant academic research and scientific papers
Propargylic and allenic carbocycle synthesis through palladium-catalyzed dearomatization reaction
Peng, Bo,Feng, Xiujuan,Zhang, Xin,Zhang, Sheng,Bao, Ming
experimental part, p. 2619 - 2627 (2010/06/17)
The dearomatization reaction of benzylic chlorides (1a?k), chloromethylnaphthalenes (1l?r), and naphthalene allyl chlorides (3a?d) with allenyltributyltin proceeded smoothly in the presence of Pd(PPh 3)4 catalyst at room temperature to give the corresponding propargylated and/or allenylated dearomatization products (5, 5′; 6, 6′; and 7, respectively) in high to fair yields. The reaction of 1a?k proceeded smoothly in the presence of TBAF, whereas it was not necessary to use TBAF as an additive in the reactions of 1l?k and 3a?d. These reactions provided a new and efficient method for the synthesis of propargylic and allenic carbocycles.
Rearrangements of (2'-Propinyl)cyclohexadienols and -semibenzenes
Lukac, Josef,Heimgartner, Heinz
, p. 355 - 370 (2007/10/02)
The acid catalyzed dienol-benzene rearrangement of 3- and 5-methyl-substituted (2'-propinyl)cyclohexadienols has been investigated.Treatment of the dienols with CF3COOH in CCl4 yields allenyl- and (2'-propinyl)benzenes via - and -sigmatropic rea
