97190-65-3Relevant academic research and scientific papers
Combined Use of Kinetic and Crystallographic Data to Probe the Hydrolysis of a Simple Amide
Camilleri, Patrick,Carey, Joseph V.,Odell, Barbara,Williams, David J.
, p. 591 - 596 (1988)
The base-catalysed hydrolysis of the formyl derivative of a nitromethylene heterocycle is described.A Broensted plot of the data gives β = 0.56.The point for water falls on the Broensted line, which indicates that the water-catalysed hydrolysis involves a transition state in which one molecule of water, acting as a base, abstracts a proton from a nucleophilic water molecule.This result is supported by proton inventory studies.We have also analysed the crystal structures of the amide and of its product of hydrolysis and have identified structural features that are thought to be responsible for facile hydrolysis.
3-Oxomethyl-2-(1-nitro-2-oxoethylidene)-tetrahydro-2H-1,3-thiazines
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, (2008/06/13)
Novel compounds defined in the title, useful as insecticides.
5,6-Dihydro-4H-1,3-thiazine-2-carboxaldehyde oxime useful as insecticides
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, (2008/06/13)
5,6-Dihydro-4H-1,3-thiazine-2-carboxaldehyde oxime useful as an insecticide.
3,4-Dihydro-7-hydroxy-8-nitro-2H-pyrrolo(2,1-b)-(1,3)thiazin-6(7H)-one
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, (2008/06/13)
3,4-Dihydro-7-hydroxy-8-nitro-2H-pyrrolo(2,1-b)-(1,3)thiazin-6(7H)-one, useful as an insecticide.
1,1,1-Trichloro-3-nitro-3-(tetrahydro-2H-1,3-thiazin-2-ylidene)-2-propanone
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, (2008/06/13)
The title compound, useful as an insecticide.
3-(5,6-Dihydro-4H-1,3-thiazin-2-yl)-3-nitro-2-propenoic acid
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, (2008/06/13)
The title compound, useful as an insecticide.
3,4-Dihydro-8-nitro-2H-pyrrolo(2,1-B)(1,3)thiazin-7(6H)-one
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, (2008/06/13)
3,4-DIHYDRO-8-NITRO-2H-pyrrolo(2,1-b)(1,3)-thiazin-7(6H)-one, useful as an insecticide.
2-(Dihalonitromethyl)-5,6-dihydro-4H-1,3-thiazines
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, (2008/06/13)
Novel insecticidal 2-(dihalonitromethyl)-5,6-dihydro-4H-1,3-thiazines.
