97204-52-9Relevant academic research and scientific papers
ACYCLIC STEREOSELECTION USING RELATIVE 1,2-ASYMMETRIC INDUCTION. SELECTIVE SYNTHESIS OF (+)-BLASTMYCINONE
Uchiyama, Hiroshi,Kobayashi, Yuichi,Sato, Fumie
, p. 467 - 470 (1985)
(+)-Blastmycinone has been synthesized based on the stereoselective addition reaction of 1-trimethylsilylvinylmagnesium bromide with (-)-(R)-2-butyl-trimethylsilylbut-3-enal.
DIASTEREO- AND ENANTIOSELECTIVE PREPARATION OF β-ALKYLHOMOALLYLIC ALCOHOLS SYNTHESIS OF SERRICORNIN AND CORYNOMYCOLIC ACID
Kobayashi, Yuichi,Kitano, Yasunori,Takeda, Yoshiyuki,Sato, Fumie
, p. 2937 - 2944 (2007/10/02)
A new and efficient method for the preparation of four possible stereoisomers of β-alkylhomoallylic alcohols 1 has been developed which is based on the diastereoselective addition of nucleophiles to optically active α-alkyl-β-trimethylsilyl-β,γ-unsaturate
