97209-98-8Relevant academic research and scientific papers
(Bromodimethyl)sulfonium bromide-mediated thiolysis of epoxides: An easy access to -hydroxy sulfides and benzoxathiepinones in solvent-free conditions
Shailaja,Manjula,Rao, B. Vittal
experimental part, p. 3629 - 3639 (2011/02/22)
A mild, rapid and highly regioselective opening of epoxides by mercaptans to bη-hydroxy sulfides and benzoxathiepinones has been achieved in excellent yields, using catalytic amount of (bromodimethyl)sulfonium bromide in solvent free reaction conditions.
KINETICS AND MECHANISM OF THE REACTION BETWEEN ALKYLOXIRANES AND ALKANETHIOLS IN THE PRESENCE OF BASIC CATALYSTS
Chlebicki, Jan,Cichacz, Zbigniew
, p. 139 - 147 (2007/10/02)
Rate constants and activation parameters have been determined for the reaction of methyloxirane and ethyloxirane with alkanethiols.The mechanism of this reaction in the resence of basic catalysts is proposed, and its kinetic equation is presented.
REACTIONS OF OXIRANES WITH ALKYLTHIOLS
Chlebicki, Jan,Cichacz, Zbigniew
, p. 485 - 494 (2007/10/02)
Alkyl-2-hydroxyalkyl sulfides and their oxyalkylenated adducts were obtained in the reaction of oxirane or methyloxirane with C4-C12 alkylthiols in presence of basic or acidic catalysts.The sulfides were further oxidized to sulfoxides and sulfones.
