97249-34-8

Upstream product

• 75583-57-2 lithium bis(dimethyl(phenyl)silyl)cuprate 
• 97249-33-7 (1Z,3R*,5S*,6S*,7S*)-3,6,8-Triacetoxy-3,5,7-trimethyl-1-phenyloct-1-ene 
• 97249-33-7 (1E,3R*,5R*,6R*,7R*)-3,6,8-Triacetoxy-3,5,7-trimethyl-1-phenyloct-1-ene 
• 97249-29-1 (R)-3-((4R,5R)-2,2,5-Trimethyl-[1,3]dioxan-4-yl)-butyronitrile 
• 97249-30-4 (4R*,5R*,6R*)-5,7-Dihydroxy-5,7-O-isopropylidene-4,6-dimethylheptan-2-one 
• 97249-32-6 (2R*,3R*,4R*,6S*)-2,4,6-Trimethyl-8-phenyloct-7-yne-1,3,6-triol 
• 97249-32-6 (2R*,3R*,4R*,6R*)-2,4,6-Trimethyl-8-phenyloct-7-yne-1,3,6-triol 
• 97249-31-5 (3R*,5S*,6S*,7S*)-6,8-Dihydroxy-6,8-O-isopropylidene-3,5,7-trimethyl-1-phenyloct-1-yn-3-ol 
• 97249-31-5 (3R*,5R*,6R*,7R*)-6,8-Dihydroxy-6,8-O-isopropylidene-3,5,7-trimethyl-1-phenyloct-1-yn-3-ol 

Downstream Products

• 97249-35-9 Acetic acid (E)-(1S,2S,4R)-1-((S)-2-acetoxy-1-methyl-ethyl)-2,4-dimethyl-6-phenyl-hex-5-enyl ester 
• 945-06-2 Prelog-Djerassi lactonic acid 

Relevant academic research and scientific papers

A SYNTHESIS OF THE PRELOG-DJERASSI LACTONE USING OPEN-CHAIN STEREOCONTROL BASED ON ALLYLSILANE CHEMISTRY

A stereocontrolled synthesis of the Prelog-Djerassi lactone (28) is described; all the stereocontrol sterms from the high diastereoselectivity of electrophilic attack on a double bond adjacent to a chiral centre carrying a silyl group.