97250-47-0Relevant academic research and scientific papers
PALLADIUM-CATALYZED ADDITION REACTION OF POLYHALOALKANES TO OLEFINS
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 393 - 398 (1985)
Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions.BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes.The reaction is accel
