97250-88-9Relevant academic research and scientific papers
HIGH DIASTEREOSELECTIVITY IN LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS.
Gennari, Cesare,Bernardi, Anna,Cardani, Silvia,Scolastico, Carlo
, p. 797 - 800 (1985)
BF3OEt2 mediated aldol condensations of thioester silyl ketene acetals are stereoconvergent, and exhibit high internal (anti) and relative (Cram) diastereoselectivity.
LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS
Gennari, Cesare,Beretta, M. Grazia,Bernardi, Anna,Moro, Giorgio,Scolastico, Carlo,Todeschini, Roberto
, p. 893 - 910 (2007/10/02)
BF3-OEt2 mediated thioester silylketene acetal additions to aldehydes are stereoconvergent and give high anti-syn ratios and good chemical yields.An acyclic transition state model was hypothesized in order to account for the observed selectivity.Theoretic
