97263-25-7

Basic information

• Product Name: [Ru(NO)(P(C₆H₅)3)(C₅H₅N)Br₃]
• CAS NO: 97263-25-7
• Molecular Weight: 712.18
• Mol File: 97263-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(NO)(P(C₆H₅)3)(C₅H₅N)Br₃](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(NO)(P(C₆H₅)3)(C₅H₅N)Br₃](97263-25-7)
• EPA Substance Registry System: [Ru(NO)(P(C₆H₅)3)(C₅H₅N)Br₃](97263-25-7)

Safety Data

• Hazardous Substances Data: 97263-25-7(Hazardous Substances Data)

Upstream product

• 13444-89-8 nitrosyl tribromide 
• 97286-22-1 [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br] 
• 13444-87-6 nitrosyl bromide 
• 97286-31-2 [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)(CN)] 

Relevant articles and documents

Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide

Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60percent by a general reaction of 5-C5H5)(PPh3)L>+X- (L = 2,2'-bipyridine or 1,10-phenanthroline, X- = Cl- or Br-) or 5-C5H5)(PPh3)(L)X> (L = PPh3, pyridine, 3-picoline, 4-picoline, 1/2(2,2'-bipyridine), or 1/2(1,10-phenanthroline); X- = Cl-, Br-, I-, CN-, NCS-, H-, or SnCl3-) with NOBr3 and N2O3.In these complexes NO seems to bind with the metal ion as NO+.The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes.The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, instead nitrito complexes were isolated in which spectroscopic evidence (ir, 1H nmr) suggest ?-interaction of one of the phenyl rings of the triphenylphosphine ligand to the ruthenium center.All products are characterised by elementary microanalyses, conductivity, magnetic moment measurements, electronic, ir, 1H nmr spectral data.