97276-95-4

Basic information

• Product Name: Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-b- D-glucopyranoside
• Synonyms: Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-β- D-glucopyranoside;Methyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-b-D-glucopyranoside;Methyl 2-Deoxy-2-(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-4,6-O-(phenylMethylene)-
• CAS NO: 97276-95-4
• Molecular Formula: C₂₂H₂₁NO₇
• Molecular Weight: 411.408
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives;Aromatics
• Mol File: 97276-95-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 614.4°C at 760 mmHg
• Flash Point: 325.4°C
• Appearance: /
• Density: 1.45g/cm³
• Vapor Pressure: 5.92E-16mmHg at 25°C
• Refractive Index: 1.659
• CAS DataBase Reference: Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-b- D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-b- D-glucopyranoside(97276-95-4)
• EPA Substance Registry System: Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-b- D-glucopyranoside(97276-95-4)

Safety Data

• Hazardous Substances Data: 97276-95-4(Hazardous Substances Data)

Usage

Uses

Methyl 4,6-O-Benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside is used in the synthesis of the O-specific polysaccharide of Shigelia flexneri.

InChI:InChI=1/C22H21NO7/c1-27-22-16(23-19(25)13-9-5-6-10-14(13)20(23)26)17(24)18-15(29-22)11-28-21(30-18)12-7-3-2-4-8-12/h2-10,15-18,21-22,24H,11H2,1H3

Upstream product

• 7772-87-4 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl chloride 
• 10028-45-2 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl bromide 
• 76101-13-8 methyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 70831-94-6 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-D-glucopyranosyl bromide 
• 76101-14-9 methyl-2-desoxy-2-phthalimido-β-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 774-48-1 (diethoxymethyl)benzene 

Downstream Products

• 100836-88-2 Galβ(1-3)GlcNAcβ(1-)OCH3 
• 102271-18-1 methyl 2-acetamido-2-deoxy-3-O-<2-O-(α-L-fucopyranosyl)-β-D-galactopyranosyl>-β-D-glucopyranoside 
• 141542-04-3 2-[(4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-8-((2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione 
• 141542-05-4 Methyl 4,6-O-benzylidene-3-O-(4,6-O-benzylidene-β-D-galactopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 141542-06-5 Methyl 3-O-(3-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl)-4,6-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 141542-08-7 Methyl O-(2,3,4-tri-O-benzoyl-α-L-fucopyranosyl)-(1->2)-O-(3-O-benzoyl-β-D-galactopyranosyl-(1->3)-2-deoxy-2-phthalimido)-β-D-glucopyranoside 
• 141542-09-8 methyl O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-(1->2)-O-(3-O-benzoyl-β-D-galactopyranosyl)-(1->3)-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 129114-77-8 C₄₁H₄₀F₉NO₁₈S₃ 
• 129114-78-9 C₄₈H₄₉F₆NO₁₇S₂ 
• 129090-88-6 C₄₃H₄₅F₆NO₁₆S₂ 
• 100638-50-4 methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 129090-89-7 methyl 4-O-<3-O-allyl-4,6-O-(4-methoxybenzylidene)-β-D-galactopyranosyl>-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 129090-90-0 2-{(2R,3R,4R,5S,6R)-5-[(2S,3R,4S,5S,6R)-4-Allyloxy-3,5-dihydroxy-6-(4-methoxy-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-4-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-yl}-isoindole-1,3-dione 
• 129090-86-4 2-[(2R,3R,4R,5S,6R)-5-((2S,3R,4S,5S,6R)-4-Allyloxy-6-allyloxymethyl-3,5-dihydroxy-tetrahydro-pyran-2-yloxy)-4-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-yl]-isoindole-1,3-dione 

Relevant articles and documents

Efficient Synthesis of 3,6-Dideoxy-β-D-arabino-hexopyranosyl-Terminated LacdiNac Glycan Chains of the Trichinella spiralis Parasite

The synthesis of a linear trisaccharide epitope of the Trichinella spiralis N-linked glycan, in a form amenable to glycoconjugate formation, is reported. The trisaccharide contains the synthetically challenging LacdiNAc [β-GalpNAc(1→4)-β-GlcpNAc] element,

Preparation of disaccharides having a β-D-mannopyranosyl group from N-phthaloyllactosamine derivatives by double or triple SN2 substitution

Condensation of 1,2,3,4,6-penta-O-acetyl-β-D-galactopyranose with methyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside, followed by alkaline methanolysis, gave a derivative of lactosamine that has an unsubstituted β-D-galactopyranosyl group.Tr

SYNTHESIS OF THE PRINCIPAL CHAIN OF THE o-ANTIGENIC POLYSACCHARIDES OF Shigella Flexneri. COMMUNICATION 4. SYNTHESIS OF 1,3-DI-O-ACETYL-4,6-DI-O-BENZOYL-2-DESOXY-2-PHTHALIMIDO-D-GLUCOPYRANOSE AND 1-O-ACETYL-2-O-(3-O-ACETYL-4,6-DI-O-BENZOYL-2-DESOXY-2-PHTHALIMIDO-β-D-GLUCOPYRANOSYL)-...

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