97336-78-2Relevant academic research and scientific papers
Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates
Endo, Kohei,Hirokami, Munenao,Shibata, Takanori
scheme or table, p. 3469 - 3472 (2010/08/05)
The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasu
Carbanion Photochemistry. 8 Effect of Substituent Reduction Potential on the Ground- and Excited-State Isomerization of 2-Aryl-1,3-diphenylpropenyl Anions.
Tolbert, Laren M.,Ali, M. Zaki
, p. 3288 - 3295 (2007/10/02)
The ground- and excited-state chemistry of 2-aryl-1,3-diphenylpropenyl anions is readily described by a Hueckel model.Because of the antisymmetric nonbonding molecular orbital, in the ground state none of the charge is distributed in the central ring.In the excited state, a nonbonding electron is promoted to a symmetric orbital which is localized on the central aryl ring.Thus lowering the reduction potential of the substituent stabilizes the excited state toward electron-transfer-initiated isomerization of cis-stilbene.Conversely, the more stabilized excited states undergo more efficient E,Z isomerization.Finally, if the central substituent is a 4-chlorophenyl group, photoinduced chloride elimination occurs.
