97350-99-7

Basic information

• Product Name: erythro N-p-tolyl-2-methyl-1-phenyl-3-butenylamine
• CAS NO: 97350-99-7
• Molecular Weight: 251.371
• Mol File: 97350-99-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: erythro N-p-tolyl-2-methyl-1-phenyl-3-butenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: erythro N-p-tolyl-2-methyl-1-phenyl-3-butenylamine(97350-99-7)
• EPA Substance Registry System: erythro N-p-tolyl-2-methyl-1-phenyl-3-butenylamine(97350-99-7)

Safety Data

• Hazardous Substances Data: 97350-99-7(Hazardous Substances Data)

Upstream product

• 1613-92-9 (E)-N-benzylidene-4-toluidine 
• 22032-77-5 (E)-crotylmagnesium chloride 
• 76371-55-6 ((E)-9-But-2-enyl)-9-bora-bicyclo[3.3.1]nonane 

Relevant articles and documents

Diastereofacial Selectivity in the Reaction of Allylic Organometallic Compounds with Imines. Stereoelectronic Effect of Imine Group

The diastereofacial selectivity in the reaction of crotyl organometallic compounds (4) (M = Li+, Mg, B, and Sn) with imines (3) is investigated.The reaction of ordinary imines produces the erythro isomer (5) predominantly regardless of the metal (M).With increase of the steric bulk of the R group or with aryl substituent in the R' group, the threo isomer (6) predominates in the reaction of crotyl-9-BBN.The ratio of erythro (11)/threo (12) in the reaction of pent-3-en-2-yl-9-BBN (9) is higher then the ratio of erythro (5)/threo (6) in the reaction of crotyl-9-BBN itself.On the basis of these observations, the transition-state geometry is discussed.