97355-16-3

Basic information

• Product Name: N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)amine
• Synonyms: N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)amine
• CAS NO: 97355-16-3
• Molecular Weight: 425.655
• Mol File: 97355-16-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)amine(97355-16-3)
• EPA Substance Registry System: N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)amine(97355-16-3)

Safety Data

• Hazardous Substances Data: 97355-16-3(Hazardous Substances Data)

Upstream product

• 227030-46-8 N,N-bis(2-hydroxy-3,5-di-tert-butylphenyl)ammonium trifluoroacetate 
• 1020-31-1 3,5-Di-tert-butylcatechol 

Downstream Products

• 936947-51-2 K⁽¹⁺⁾*N(C₆H₂(C(CH₃)3)2O)2^(1-)=N(C₆H₂(C(CH₃)3)2O)2K 
• 130681-31-1 {(C(CH₃)3)2C₆H₂O}2NSb(CH₃C₆H₄)2 
• 130681-43-5 (CH₃C₆H₃O)2NHSb(CH₃C₆H₄)3 

Relevant articles and documents

Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide

Gallium hydrides stabilised by primary and secondary amines are scarce due to their propensity to eliminate dihydrogen. Consequently, their reactivity has received limited attention. The synthesis of two novel gallium hydride complexes HGa(THF)[ON(H)O] and H2Ga[μ2-ON(H)O]Ga[ON(H)O] ([ON(H)O]2?=N,N-bis(3,5-di-tert-butyl-2-phenoxy)amine) is described and their reactivity towards aldehydes and ketones is explored. These reactions afford alkoxide-bridged dimers through 1,2-hydrogallation reactions. The gallium hydrides can be regenerated through Ga?O/B?H metathesis from the reaction of such dimers with pinacol borane (HBpin) or 9-borabicyclo[3.3.1]nonane (9-BBN). These observations allowed us to target the catalytic reduction of carbonyl substrates (aldehydes, ketones and carbon dioxide) with low catalyst loadings at room temperature.